Er-Yb玻璃低应力减反射膜的研制

Development of low-stress anti-reflective coatings for Er-Yb glass

  • 摘要: 随着激光技术的快速发展,Er-Yb玻璃在人眼安全激光器中得到广泛应用,但Er-Yb玻璃作为激光器谐振腔的基底时,表面膜层附着力差、应力大的问题降低了激光器的输出效率。采用Ta2O5和SiO2作为高低折射率材料,利用离子辅助沉积技术,在Er-Yb玻璃基底上研制了低应力的减反射膜。通过使用COMSOL软件建立热仿真模型,引入SiO2粘接层,降低膜层热应力,解决了膜层脱膜的问题;通过设计梯度工艺参数,建立了残余应力与离子源能量和膜层厚度的数学模型,选取合适的工艺参数,制备了低应力减反射膜,在(1535±3) nm波长平均反射率为0.069%,膜层残余应力为−8.61 MPa,并且通过了附着力、水煮及湿热试验,满足使用要求。

     

    Abstract:
    Objective Er-Yb glass is a critical component in 1535 nm eye-safe laser systems. When such a laser enters the human eye, it is strongly absorbed by water molecules present in the cornea and lens. The eye-safe irradiation threshold of this laser is 106 times higher than that of Nd:YAG lasers, highlighting its significant potential in laser medicine, lidar, and military applications. However, Er-Yb glass exhibits several inherent limitations, including high hydrophilicity, a large thermal expansion coefficient, low hardness, and a low glass transition temperature. These properties often lead to substantial thermal stress and poor film adhesion during coating processes. Furthermore, excessive residual stress within the coating during laser operation can result in laser-induced ablation. Therefore, it is essential to develop low-stress thin films with superior adhesion on Er-Yb glass substrates to meet the reliability requirements of practical eye-safe laser systems.
    Methods This paper employs COMSOL Multiphysics software to develop a thermal-stress simulation model of the coating. By introducing a SiO2 bonding layer to alleviate thermal stresses in the coating, the challenge of coating delamination is effectively addressed. By designing of gradient process parameters, a mathematical model that correlates residual stress to ion source energy and coating thickness is established. Optimal process parameters are screened to prepare low-stress antireflective coatings.
    Results and Discussions After introducing a SiO2 bonding layer, COMSOL Multiphysics showed that the thermal stress within the multilayer film was reduced from 417 MPa to 388 MPa (Fig.3), corresponding to a reduction of 29 MPa. Specifically, the thermal stress in the first layer of the multilayer film was reduced from 417 MPa to 127 MPa (Fig.4). Furthermore, adhesion tests confirmed the absence of coating delamination (Fig.5). Through systematic tuning of the ion source parameters for the Ta2O5 layer and the thickness-related process parameters for the SiO2 layer, a mathematical model was developed to achieve stress matching. This enabled the preparation of a low-stress antireflective coating exhibiting a residual stress of −8.61 MPa (Tab.11) and a reflectance of 0.069% (Fig.10).
    Conclusions The paper adopts electron beam thermal evaporation ion-assisted deposition (IAD) technology, with Ta2O5 and SiO2 as coating materials, for the design and fabrication of near-infrared antireflective coatings on Er-Yb glass substrates that meet adhesion requirements and possess low-stress characteristics. COMSOL Multiphysics software was employed to develop a thermal-stress simulation model. It was revealed that with SiO2 serving as the bonding layer, the thermal stress in the first film layer was reduced from 417 MPa to 127 MPa, thereby effectively addressing the problem of film delamination. Through the establishment of a mathematical model correlating residual stress with ion source energy and film thickness, the deposition process was optimized, enabling the preparation of a low-stress film with a residual stress of −8.61 MPa. The resulting film successfully passed adhesion, water boiling, and damp heat tests, exhibiting an average reflectance of 0.069% within the wavelength range of (1535±3) nm, which satisfies the operational requirements of Er-Yb lasers. To further reduce the film stress, future research will concentrate on investigating the influence of interfacial stress on the residual film stress.

     

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