Volume 48 Issue 11
Dec.  2019
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Zhang Lei, Wu Hao-Ran, Dong Tao-Tao, Zhang Ze-Qi, Wang Qiang, Zhang Hao-Li. Optical limiting two-dimensional antimonene via electron irradiation[J]. Infrared and Laser Engineering, 2019, 48(11): 1103004-1103004(5). doi: 10.3788/IRLA201948.1103004
Citation: Zhang Lei, Wu Hao-Ran, Dong Tao-Tao, Zhang Ze-Qi, Wang Qiang, Zhang Hao-Li. Optical limiting two-dimensional antimonene via electron irradiation[J]. Infrared and Laser Engineering, 2019, 48(11): 1103004-1103004(5). doi: 10.3788/IRLA201948.1103004

Optical limiting two-dimensional antimonene via electron irradiation

doi: 10.3788/IRLA201948.1103004
  • Received Date: 2019-07-06
  • Rev Recd Date: 2019-08-05
  • Publish Date: 2019-11-25
  • Antimonene was prepared through liquid phase exfoliation of bulk materials. The as-prepared sample was characterized by scanning electron microscope (SEM), ultraviolet-visible (UV-vis) absorption spectroscopy, and Raman scattering spectroscopy in details. Broad absorption from ultraviolet to visible region was observed in the UV-vis absorption spectra. Two typical peaks assigned to Sb were detected in Raman spectra. A flat typical structure corresponding to two-dimensional materials was observed in microscopic characterization. Then Z-scan technique was utilized to test the third-order nonlinear optical properties of the sample. The as-prepared antimonene exhibited saturation absorption when excited by a laser source with pulse width of 4 ns and wavelength of 532 nm. The nonlinear absorption coefficient was -7.8610-11 m/W. Upon electron irradiation, antimonene was successfully transformed into optical limiting materials, which exhibited reverse saturable absorption with a nonlinear absorption coefficient of 8.6910-11 m/W.
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    [2] Pumera M, Sofer Z. 2D monoelemental arsenene, antimonene, and bismuthene:beyond black phosphorus[J]. Adv Mater, 2017, 29(21):1605299.
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Optical limiting two-dimensional antimonene via electron irradiation

doi: 10.3788/IRLA201948.1103004
  • 1. State Key Laboratory of Applied Organic Chemistry(SKLAOC),College of Chemistry and Chemical Engineering,Lanzhou University,Lanzhou 730000,China

Abstract: Antimonene was prepared through liquid phase exfoliation of bulk materials. The as-prepared sample was characterized by scanning electron microscope (SEM), ultraviolet-visible (UV-vis) absorption spectroscopy, and Raman scattering spectroscopy in details. Broad absorption from ultraviolet to visible region was observed in the UV-vis absorption spectra. Two typical peaks assigned to Sb were detected in Raman spectra. A flat typical structure corresponding to two-dimensional materials was observed in microscopic characterization. Then Z-scan technique was utilized to test the third-order nonlinear optical properties of the sample. The as-prepared antimonene exhibited saturation absorption when excited by a laser source with pulse width of 4 ns and wavelength of 532 nm. The nonlinear absorption coefficient was -7.8610-11 m/W. Upon electron irradiation, antimonene was successfully transformed into optical limiting materials, which exhibited reverse saturable absorption with a nonlinear absorption coefficient of 8.6910-11 m/W.

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