Zhang Lei, Wu Hao-Ran, Dong Tao-Tao, Zhang Ze-Qi, Wang Qiang, Zhang Hao-Li. Optical limiting two-dimensional antimonene via electron irradiation[J]. Infrared and Laser Engineering, 2019, 48(11): 1103004-1103004(5). doi: 10.3788/IRLA201948.1103004
Citation:
|
Zhang Lei, Wu Hao-Ran, Dong Tao-Tao, Zhang Ze-Qi, Wang Qiang, Zhang Hao-Li. Optical limiting two-dimensional antimonene via electron irradiation[J]. Infrared and Laser Engineering, 2019, 48(11): 1103004-1103004(5). doi: 10.3788/IRLA201948.1103004
|
Optical limiting two-dimensional antimonene via electron irradiation
- 1.
State Key Laboratory of Applied Organic Chemistry(SKLAOC),College of Chemistry and Chemical Engineering,Lanzhou University,Lanzhou 730000,China
- Received Date: 2019-07-06
- Rev Recd Date:
2019-08-05
- Publish Date:
2019-11-25
-
Abstract
Antimonene was prepared through liquid phase exfoliation of bulk materials. The as-prepared sample was characterized by scanning electron microscope (SEM), ultraviolet-visible (UV-vis) absorption spectroscopy, and Raman scattering spectroscopy in details. Broad absorption from ultraviolet to visible region was observed in the UV-vis absorption spectra. Two typical peaks assigned to Sb were detected in Raman spectra. A flat typical structure corresponding to two-dimensional materials was observed in microscopic characterization. Then Z-scan technique was utilized to test the third-order nonlinear optical properties of the sample. The as-prepared antimonene exhibited saturation absorption when excited by a laser source with pulse width of 4 ns and wavelength of 532 nm. The nonlinear absorption coefficient was -7.8610-11 m/W. Upon electron irradiation, antimonene was successfully transformed into optical limiting materials, which exhibited reverse saturable absorption with a nonlinear absorption coefficient of 8.6910-11 m/W.
-
References
[1]
|
Miao J S, Zhang L, Wang C. Black phosphorus electronic and optoelectronic devices[J]. 2D Materials, 2019, 6(3):032003. |
[2]
|
Pumera M, Sofer Z. 2D monoelemental arsenene, antimonene, and bismuthene:beyond black phosphorus[J]. Adv Mater, 2017, 29(21):1605299. |
[3]
|
Ji J, Song X, Liu J, et al. Two-dimensional antimonene single crystals grown by van der Waals epitaxy[J]. Nat Commun, 2016, 7:13352. |
[4]
|
Wang X, Song J, Qu J. Antimonene:From experimental preparation to practical application[J]. Angew Chem Int Ed Engl, 2019, 58(6):1574-1584. |
[5]
|
Novoselov K S, Geim A K, Morozov S V, et al. Electric field effect in atomically thin carbon films[J]. Science, 2004, 306(5696):666-669. |
[6]
|
Liu Z, Zhang X, Yan X, et al. Nonlinear optical properties of graphene-based materials[J]. Chinese Science Bulletin, 2012, 57(23):2971-2982. |
[7]
|
Wang K, Wang J, Fan J, et al. Ultrafast saturable absorption of two-dimensional MoS2 nanosheets[J]. ACS Nano, 2013, 7(10):9260-9267. |
[8]
|
Chen Y, Jiang G, Chen S, et al. Mechanically exfoliated black phosphorus as a new saturable absorber for both Q-switching and Mode-locking laser operation[J]. Opt Express, 2015, 23(10):12823-12833. |
[9]
|
Liu Z W, Gan F, Dong N N, et al. Fabrication and nonlinear optical characterization of fluorinated zinc phthalocyanine covalently modified black phosphorus/PMMA films using the nanosecond Z-scan technique[J]. Journal of Materials Chemistry C, 2019, 7(35):10789-10794. |
[10]
|
Yang Q Q, Liu R T, Huang C, et al. 2D bismuthene fabricated via acid-intercalated exfoliation showing strong nonlinear near-infrared responses for mode-locking lasers[J]. Nanoscale, 2018, 10(45):21106-21115. |
[11]
|
Liu G, Zhang F, Wu T, et al. Single- and dual-wavelength passively mode-locked erbium-doped fiber laser based on antimonene saturable absorber[J]. IEEE Photonics Journal, 2019, 11(3):1-11. |
-
-
Proportional views
-