铟酞菁/氧化石墨烯高分子材料的制备及非线性光限幅性能研究

马鹏飞; 刘大军; 周奋国

doi:10.3788/IRLA202049.0107001

铟酞菁/氧化石墨烯高分子材料的制备及非线性光限幅性能研究

doi: 10.3788/IRLA202049.0107001

长春理工大学化学与环境工程学院, 吉林长春 130022

基金项目:

吉林省自然科学基金（20170101107JC）；吉林省重点科技研发项目（20180201083GX）；长春理工大学科技创新基金（CX2015006）

详细信息

作者简介:
马鹏飞(1987-),男,讲师,硕士,主要从事三阶非线性和光限幅方面的研究。Email:119966984@qq.com

中图分类号: O473

Study on preparation and performance of nonlinear optical limiting of polymers material containing indium phthalocyanine and graphene oxide

School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, China

摘要: 通过共价键合将二氨基二枯丁苯氧基氯代铟酞菁（Pc）与羧基化氧化石墨烯（GO-COOH）键合在一起，得到二氨基二枯丁苯氧基氯代铟酞菁-氧化石墨烯键合产物（Pc-GO-COOH），并以键合产物为原料反应得到引发剂。以甲基丙烯酸甲酯（MMA）为聚合反应单体，通过原子转移自由基聚合（ATRP）反应得到四种不同分子量的聚合物样品。采用凝胶渗透色谱（GPC）对聚合物分子量分布测试，结果表明，所制备的聚合物的分子量分布范围较窄，聚合反应具有良好的可控性。采用Z-扫描方法对聚合物样品溶液进行的三阶非线性测试结果表明，所制备的聚合物具有优良的三阶非线性光学性质，且当聚合物的分子量分别为9 063和12 196时，三阶非线性极化率值分别为8.1×10^-11、2.1×10^-11 esu。同时对聚合物样品的光限幅性能测试结果表明，两种样品的有效激发态与基态吸收截面比分别为2.69和2.20，具有较好的光限幅能力，具有较大的应用前景。
- 二氨基二枯丁苯氧基氯代铟酞菁 /
- 氧化石墨烯 /
- 原子转移自由基聚合 /
- 三阶非线性 /
- 光限幅
Abstract: The diaminodikhunophenoxy chloride indium phthalocyanine (Pc) was covalently bonded with carboxylated GO (GO-COOH) to obtain the diaminodikhunophenoxy chloride indium phthalocyanine-graphene oxide (Pc-GO-COOH), and the bonding products as raw material of the reaction initiator. Four kinds of polymer samples with different molecular weight were obtained by atom transfer radical polymerization (ATRP) with methyl methacrylate (MMA) as polymerization monomer. The molecular weight and molecular weight distribution of the prepared polymers were tested by gel permeation chromatography (GPC). The test results show that the preparation of polymers has narrow molecular weight distribution, the polymer reaction presents good controllability. The results of third-order nonlinear optical properties test on polymer sample solution by Z-scan show that the preparation of polymer has excellent third-order nonlinear optical properties, and when the molecular weight of polymer, respectively 9 063 and 12 196, the third order nonlinear polarizability values are 8.1×10^-11 esu and 2.1×10^-11 esu. At the same time, the optical limiting performance test show the effective excitation and ground state absorption cross section ratios of the two samples are 2.69 and 2.20, respectively. It has a good limiting ability and a great application prospect.
- diaminophenoxyl chloride indium phthalocyanine /
- graphene oxide /
- atom transfer radical polymerization /
- third-order nonlinear /
- optical limiting

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铟酞菁/氧化石墨烯高分子材料的制备及非线性光限幅性能研究

doi: 10.3788/IRLA202049.0107001

作者简介:
马鹏飞(1987-),男,讲师,硕士,主要从事三阶非线性和光限幅方面的研究。Email:119966984@qq.com

Study on preparation and performance of nonlinear optical limiting of polymers material containing indium phthalocyanine and graphene oxide

计量

铟酞菁/氧化石墨烯高分子材料的制备及非线性光限幅性能研究

doi: 10.3788/IRLA202049.0107001

长春理工大学化学与环境工程学院, 吉林长春 130022

作者简介:
马鹏飞(1987-),男,讲师,硕士,主要从事三阶非线性和光限幅方面的研究。Email:119966984@qq.com

English Abstract

Study on preparation and performance of nonlinear optical limiting of polymers material containing indium phthalocyanine and graphene oxide

School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, China

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铟酞菁/氧化石墨烯高分子材料的制备及非线性光限幅性能研究

doi: 10.3788/IRLA202049.0107001

作者简介: 马鹏飞(1987-),男,讲师,硕士,主要从事三阶非线性和光限幅方面的研究。Email:119966984@qq.com

Study on preparation and performance of nonlinear optical limiting of polymers material containing indium phthalocyanine and graphene oxide

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铟酞菁/氧化石墨烯高分子材料的制备及非线性光限幅性能研究

doi: 10.3788/IRLA202049.0107001

长春理工大学 化学与环境工程学院, 吉林 长春 130022

作者简介: 马鹏飞(1987-),男,讲师,硕士,主要从事三阶非线性和光限幅方面的研究。Email:119966984@qq.com

English Abstract

Study on preparation and performance of nonlinear optical limiting of polymers material containing indium phthalocyanine and graphene oxide

School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, China

全文HTML

目录

作者简介:
马鹏飞(1987-),男,讲师,硕士,主要从事三阶非线性和光限幅方面的研究。Email:119966984@qq.com

长春理工大学化学与环境工程学院, 吉林长春 130022

作者简介:
马鹏飞(1987-),男,讲师,硕士,主要从事三阶非线性和光限幅方面的研究。Email:119966984@qq.com